Abstract¶
Symmetry in quantum mechanics and how it leads to conservation laws.
Operators¶
An operator is symmetric with respect to the transformation if
If is an observable, this means neither the expectation value nor the probabilities of getting the different possible measurement outcomes of change if the state is evolved by .
Proof
Let , where is a unitary, and be an observable acting on .
Assume is symmetric under , meaning that .
Consider the expectation value of with respect to the state ,
meaning the expectation value of does not change if a state is evolved via .
Now, consider the spectral decomposition of ,
The condition then becomes
using linearity. Note that is still a projector for all ,
and each are orthogonal for different ,
this is because they are the projectors onto the eigenspace of . In order for the equality to hold (with each be associated to a unique subspace) is for . The probability of measuring the observable on the state and getting the outcomes is then
which is the same probability of measuring the observable on the state and getting the outcome .
Symmetry in Continuous Transformations¶
Continuous transformations are parameterised by real numbers which dictate the amount of transformation taking place. Such transformations include those in time, space, or rotations.
Transformations of this type are represented by the exponent of a generator operator, which is an observable. This is captured by Stone’s theorem.
The most common continuous transformations considered and the Hermitian operators (observables) that generate them are:
Unitary:
Generator: - Hamiltonian
Parameter: - time
Unitary:
Generator: - Momentum
Parameter: - displacement
Unitary:
Generator: - Angular Momentum in
Parameter: - angle (mod )
For an operator, , to be symmetric with respect to the continuous transformation, generator by the observable , it must be the case that
which is possible if and only if .
Conservation Laws¶
A value is conserved under a given transformation, , in quantum mechanics, if its expectation value does not change under that transformation.
When an observable, , was said to be symmetric with respect to a transformation , a consequence was that the expectation value of did not change if the state being considered was evolved by .
Hence, symmetries in the physical system lead to conservation laws. This is the fundamental message in the famous Noether’s theorem.
For example, a closed quantum system with Hamiltonian evolves in time via the time-evolution operator, . It can be seen that
meaning that the expectation value of does not change under time evolution. Hence, energy is conserved under time evolution in closed quantum systems (assuming the Hamiltonian is time-independent).
In general, given a systems evolves via a unitary and , then the dynamics described by are considered to be energy conserving, meaning that neither the expectation value of , nor the probability of getting each outcome (eigenvalue) of when measuring the observable, changes under the transformation .
States¶
A state is symmetric with respect to the transformation if
for some . As global phases cannot be measured, this means that the state is unchanged in any measurable way by the transformation .
Strictly speaking, the above definition is for invariance with respect to the transformation , with the definition becoming that of symmetry if . However, given a global phase is not physical in the sense that it can never be measured, the two can be used interchangeable.
Symmetric and Anti-symmetric states¶
Another notion of the symmetry of a quantum state arises when considering multipartite states. Let
be a bipartite state and let be the state for which the and systems have been swapped, . The state is symmetric if
and anti-symmetric if
This can be seen with the Bell states where
whereas
Hence, is antisymmetric whilst the other three two-qubit Bell states are symmetric.