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Symmetry

Abstract

Symmetry in quantum mechanics and how it leads to conservation laws.

Keywords:SymmetryConservations LawsExpectation ValuesNoethers Theorem

Operators

An operator AA is symmetric with respect to the transformation UU if

UAU=A[A,U]=0.U^\dagger A U = A \Longleftrightarrow [A,U] = 0.

If AA is an observable, this means neither the expectation value nor the probabilities of getting the different possible measurement outcomes of AA change if the state is evolved by UU.

Proof

Let ψH\ket{\psi} \in \mathcal{H}, ψ=Uψ\ket{\psi'} = U \ket{\psi} where UU is a unitary, and AA be an observable acting on H\mathcal{H}.

Assume AA is symmetric under UU, meaning that [A,U]=0[A,U] = 0.

Consider the expectation value of AA with respect to the state ψ\ket{\psi'},

Aψ=ψAψ,=ψUAUψ,=ψAψ,=Aψ,\begin{align*} \braket{A}_{\psi'} &= \bra{\psi'} A \ket{\psi'}, \\ &= \bra{\psi} U^\dagger A U \ket{\psi}, \\ &= \bra{\psi} A \ket{\psi}, \\ &= \braket{A}_{\psi}, \end{align*}

meaning the expectation value of AA does not change if a state is evolved via UU.

Now, consider the spectral decomposition of AA,

A=nλnPn.A = \sum_n \lambda_n P_n.

The condition UAU=AU^\dagger A U = A then becomes

nλnUPnU=nλnPn,\sum_n \lambda_n U^\dagger P_n U = \sum_n \lambda_n P_n,

using linearity. Note that UPnUU^\dagger P_n U is still a projector for all nn,

(UPnU)2=UPnUUPnU=UPnU,\big( U^\dagger P_n U \big)^2 = U^\dagger P_n U U^\dagger P_n U = U^\dagger P_n U,

and each UPnUU^\dagger P_n U are orthogonal for different nn,

tr[UPnUUPmU]=tr[PnPm]=δnm,\textrm{tr} \big[ U^\dagger P_n U U^\dagger P_m U \big] = \textrm{tr} \big[ P_n P_m \big] = \delta_{nm},

this is because they are the projectors onto the eigenspace of UAUU^\dagger A U. In order for the equality to hold (with each λn\lambda_n be associated to a unique subspace) is for Πn=UΠnU\Pi_n = U^\dagger \Pi_n U. The probability of measuring the observable AA on the state ψ\ket{\psi'} and getting the outcomes λn\lambda_n is then

P(λnA)=ψPnψ,=ψUPnUψ,=ψPnψ,\begin{align*} P(\lambda_n \vert A) &= \bra{\psi'} P_n \ket{\psi'}, \\ &= \bra{\psi} U^\dagger P_n U \ket{\psi}, \\ &= \bra{\psi} P_n \ket{\psi}, \end{align*}

which is the same probability of measuring the observable AA on the state ψ\ket{\psi} and getting the outcome λn\lambda_n.

Symmetry in Continuous Transformations

Continuous transformations are parameterised by real numbers which dictate the amount of transformation taking place. Such transformations include those in time, space, or rotations.

Transformations of this type are represented by the exponent of a generator operator, which is an observable. This is captured by Stone’s theorem.

The most common continuous transformations considered and the Hermitian operators (observables) that generate them are:

Time
Space
Rotation

Unitary: U(t)=ei H t  t  R1U(t) = e^{-\frac{i}{\hbar}~H~t} ~ \forall~t~\in~\mathbb{R}^1

Generator: HH - Hamiltonian

Parameter: tt - time

For an operator, BB, to be symmetric with respect to the continuous transformation, generator by the observable GG, it must be the case that

[U(q),B]=0,   U(q)=ei G q,[ U(q) , B ] = 0, ~ ~ ~ U(q) = e^{-\frac{i}{\hbar}~G~q},

which is possible if and only if [G,B]=0[G,B] = 0.

Conservation Laws

A value is conserved under a given transformation, UU, in quantum mechanics, if its expectation value does not change under that transformation.

When an observable, AA, was said to be symmetric with respect to a transformation UU, a consequence was that the expectation value of AA did not change if the state being considered was evolved by UU.

Hence, symmetries in the physical system lead to conservation laws. This is the fundamental message in the famous Noether’s theorem.

For example, a closed quantum system with Hamiltonian HH evolves in time via the time-evolution operator, U(t)=eiHtU(t)=e^{-\frac{i}{\hbar}Ht}. It can be seen that

[U(t),H]=0   as   [H,H]=0,[U(t), H] = 0 ~~ ~ {\rm as} ~~~ [H,H] = 0,

meaning that the expectation value of HH does not change under time evolution. Hence, energy is conserved under time evolution in closed quantum systems (assuming the Hamiltonian is time-independent).

In general, given a systems evolves via a unitary VV and [V,H]=0[V,H]=0, then the dynamics described by VV are considered to be energy conserving, meaning that neither the expectation value of HH, nor the probability of getting each outcome (eigenvalue) of HH when measuring the observable, changes under the transformation VV.

States

A state ψ\ket{\psi} is symmetric with respect to the transformation UU if

Uψ=eiθψ,U \ket{\psi} = e^{i \theta} \ket{\psi},

for some θ \theta . As global phases cannot be measured, this means that the state ψ\ket{\psi} is unchanged in any measurable way by the transformation UU.

Strictly speaking, the above definition is for invariance with respect to the transformation UU, with the definition becoming that of symmetry if θ=0 \theta = 0. However, given a global phase is not physical in the sense that it can never be measured, the two can be used interchangeable.

Symmetric and Anti-symmetric states

Another notion of the symmetry of a quantum state arises when considering multipartite states. Let

ψHAHB\ket{\psi} \in \mathcal{H}_A \otimes \mathcal{H}_B

be a bipartite state and let ψS\ket{\psi}_S be the state for which the AA and BB systems have been swapped, ψS=SWAPψ\ket{\psi}_S = {\rm SWAP} \ket{\psi}. The state ψ\ket{\psi} is symmetric if

ψS=ψ,\ket{\psi}_S = \ket{\psi},

and anti-symmetric if

ψS=ψ.\ket{\psi}_S = -\ket{\psi}.

This can be seen with the Bell states where

Φ00+=0A0B+1A1B2,=Φ00+S,\begin{align*} \ket{\Phi_{00}^{+}} &= \frac{\ket{0}_{A}\ket{0}_{B}+\ket{1}_{A} \ket{1}_{B}}{\sqrt{2}}, \\ &= \ket{\Phi_{00}^{+}}_S, \end{align*}

whereas

Φ11+=0A1B1A0B2,=Φ11+S.\begin{align*} \ket{\Phi_{11}^{+}} &= \frac{\ket{0}_{A}\ket{1}_{B}-\ket{1}_{A} \ket{0}_{B}}{\sqrt{2}}, \\ &= - \ket{\Phi_{11}^{+}}_S. \end{align*}

Hence, Φ11+\ket{\Phi_{11}^{+}} is antisymmetric whilst the other three two-qubit Bell states are symmetric.